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101.
102.
The enstatite-diopside solvus in the system Mg2Si2O6-CaMgSi2O6 has been experimentally determined within the pressure range 5–40 kbars and the temperature range 900–1500°C. Experiments involving reversal of the phase boundaries by unmixing from glass starting material and by reaction of pure clinoenstatite and diopside showed difficulty in achieving equilibration due to persistence of metastable, subcalcic clinopyroxene and to the sluggishness of reaction rate. The experimental data showed that the temperature dependence of the diopside limb is less than previously accepted. At 1500°C and 30 kbars subcalcic diopside found by Davis and Boyd (1966) is shown to be metastable with respect to enstatite and more calcic diopside of composition En42.3Di57.7. The solvus widens with increasing pressure between 5 and 40 kbars at 1200°C, but at 900°C the pressure effect on the solvus is very small. The stability relationships of the four pyroxenes, protoenstatite, enstatite, iron-free pigeonite and diopside are summarized, based on data from the literature and the present study.  相似文献   
103.
In situ X-ray diffraction measurements of KAlSi3O8-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K300,0=4. The determined parameters are V 300,0=237.6(2) Å3, K 300,0=183(3) GPa, (?K T,0/?T) P =?0.033(2) GPa K?1, a 0=3.32(5)×10?5 K?1, and b 0=1.09(1)×10?8 K?2, where a 0 and b 0 are coefficients describing the zero-pressure thermal expansion: α T,0 = a 0 + b 0 T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.  相似文献   
104.
We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10− 6 M- and 4 × 10− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH3COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH3COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.  相似文献   
105.
The P-wave velocity structure of the upper crust beneath a profile ranging from Niikappu to Samani in the southwestern foot of the Hidaka Mountains, Hokkaido, Japan was obtained through analysis of refraction and wide-angle reflection data. The mountains are characterized by high seismicity and a large gravity anomaly. The present profile crosses the source region of the 1982 Urakawa-oki earthquake (Ms 6.8). The length of the profile is 66 km striking northwest and southeast. Along the profile, 64 vertical geophones were set up and 5 shot points were chosen. For each shot, a 400–600 kg charge of dynamite was detonated. The studied area is composed of four major geological belts: Neogene sedimentary rocks, the Kamuikotan belt, the Yezo Group, and the Hidaka belt. The measurement line crosses these geological trend at an oblique angle. The structure obtained is characterized by remarkable velocity variations in the lateral direction and reflects the surface geological characteristics. A thin, high-velocity layer (HVL) was found between low-velocity materials in the central part of the profile, beneath the Kamuikotan Metamorphic Belt, at a depth ranging from 0.5 to 6 km, overthrusting toward the west on the low-velocity materials consisting of Neogene sedimentary rocks, and forming gentle folds. Outlines of the velocity structure of the Hidaka Mountains yielded by other studies have shown a large-scale overthrust structure associated with the collision of the Outer Kurile and the Outer Northern Honshu Arcs. The shallow velocity structure inferred by the present study showed a similar (although small scale) overthrust structure. The obtained structure shows that the composite tectonic force, comprising westward movement of the Outer Kurile Arc and northward movement of the Outer Northern Honshu Arc, plays an important role in the evolution of the tectonic features of the crust and upper mantle in a wide depth range beneath the Hidaka Mountains.  相似文献   
106.
We study gravitational lensing statistics, matter power spectra and the angular power spectra of the cosmic microwave background (CMB) radiation in x-matter models. We adopt an equation of state of x-matter which can express a wide range of matter from pressureless dust to the cosmological constant. A new ingredient in this model is the sound speed of the x-component, in addition to the equation of state w 0 =  p x0x0. Except for the cosmological constant case, the perturbations of x-matter itself are considered. Our primary interest is in the effect of non-zero sound speed on the structure formation and the CMB spectra. It is found that there exist parameter ranges where x-matter models are consistent with all current observations. The x-matter generally leaves imprints in the CMB anisotropy and the matter power spectrum, which should be detectable in future observations.  相似文献   
107.
The arsenic concentration in 13 water samples from wells in the thin, alluvial aquifer of the Madison River Valley, Montana, U.S.A. ranged from 26 to 150 μg/l. The Madison River, which originates in Yellowstone National Park, has a mean arsenic concentration of 51 μg/l (σ=26 μg/l), based upon very limited sampling in the study area during the main irrigation period. Groundwater arsenic concentration increases down the valley can be best correlated with the intensity of ditch irrigation in this semiarid area. No other sources of dissolved arsenic as concentrated as that of the river water have been identified. Evaporative concentration of river-derived irrigation water is believed to have been the overwhelming factor in the contamination of this shallow aquifer.  相似文献   
108.
A 3729-m-deep geothermal research well, WD-1a, provides us with a unique opportunity to study initial petrographic features of a high-temperature granite just after solidification of magma. The well succeeded in collecting three spot-cores of the Kakkonda Granite that is a pluton emplaced at a shallow depth and regarded as a heat source of the active Kakkonda geothermal system. The core samples were collected at the present formation temperatures of 370, 410 and over 500°C. These samples are granodiorite to tonalite consisting mainly of plagioclase, quartz, hornblende, biotite and K-feldspar. A sample collected at a formation temperature of over 500°C possesses the following remarkable petrographic features compared to the other two samples. Interstitial spaces are not completely sealed. K-feldspar exhibits no perthite by the exsolution of albite lamella. Quartz includes glassy melt inclusions without devitrification. Hornblende is less intensively altered to actinolite, and biotite is not altered. This study directly confirmed that perthite in K-feldspar is a recrystallization texture formed at 410–500°C based on a comparison of the in situ temperatures of the samples. Chemical compositions of minerals were analyzed to compare temperatures determined from geothermometers in several publications to the in situ temperatures of the samples.  相似文献   
109.
The 2.45-Byr-old weathering profile developed on early Proterozoic mafic volcanics located near Cooper Lake, Ontario, Canada, was examined geochemically and mineralogically for a better understanding of the atmospheric oxygen evolution. Ferrous to ferric ion, Fe(II) and Fe(III), respectively, ratios of the bulk rock samples were analyzed by Mössbauer spectrometry. The total Fe (Fe(T)) and Fe(II) concentrations decrease from 12.0 and 11.2 wt.% to 1.85 and 0.89 wt.%, respectively, from the bottom to the top of the weathering profile. The Fe(T) and Fe(II) concentrations normalized to Ti and Zr, as well as the Fe(II)/Fe(III) ratio of raw data, linearly decrease with depth toward the top, while the Fe(III) concentration remains nearly constant throughout the profile. The linear decrease of Fe(II), accompanied by the nearly constant distribution of Fe(III), is difficult to be explained by the scenario of oxidizing weathering and subsequent reducing hydrothermal alteration. The behaviors of Fe(II) and Fe(III) can be simply explained by anoxic weathering. The anoxic weathering suggests that the 2.45-Ga atmosphere was anoxic. The slight increase of Fe/(Fe+Mg) in the octahedral sites of chlorite toward the top and no Ce anomaly in the REE patterns are also consistent with anoxic weathering.  相似文献   
110.
Shear Strength Behavior of Two Landfill Clay Liners   总被引:1,自引:0,他引:1  
Direct shear tests were conducted to obtain both the shear strength of compacted clay liners (CCLs) specimens and the interface shear strength between compacted clay liner and base soil. These experiments were conducted under the conditions of five different water contents. The experimental results show that shear strength of both CCLs and CCLs/base interface decreases with the increase in the water content of CCLs and base soil. In addition, the considerate concentration of NaCl in leachate has no deteriorating effect on the shear strength of liners. Triaxial shear tests were also conducted on clay liner specimens to obtain total and effective shear strength under a fast compression. The shear strength c‘=100 kPa for sand-bentonite, respectively. These results indicate that the compacted clay-bentonite shows normal consolidation, but that the compacted sand-bentonite exhibits over-consolidation.  相似文献   
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